A cubic dipole lattice of water molecules trapped inside carbon cages.

نویسندگان

  • Shinobu Aoyagi
  • Norihisa Hoshino
  • Tomoyuki Akutagawa
  • Yuki Sado
  • Ryo Kitaura
  • Hisanori Shinohara
  • Kunihisa Sugimoto
  • Rui Zhang
  • Yasujiro Murata
چکیده

We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.

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عنوان ژورنال:
  • Chemical communications

دوره 50 5  شماره 

صفحات  -

تاریخ انتشار 2014